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After Peter Venkman arrived outside of Heaven, he attempted to enlist the help of the Angels guarding the gates, but they could not enter Purgatory. An equal number of Angels and Demons guard the borders of Purgatory and maintain the balance of realms. However, when Peter passed through The Pipeline nearly asphyxiated, the Angels were free to act and appeared to have helped restore the Ghostbusters and Ecto-1 to normal and out of the East River. They were well aware of the Ghostbusters exploits against the supernatural, it seems.